تعیین دمای تشکیل، فوگاسیته اکسیژن و نسبت Ce4+/Ce3+ با استفاده از شیمی زیرکن دردایک¬های پگماتیتی ملاير- بروجرد- شازند، پهنه سنندج-سیرجان
محورهای موضوعی :
مجید قاسمی سیانی
1
(دانشگاه خوارزمی)
کلید واژه: شیمی زیرکن# دایک¬های پگماتیتی# ضریب توزیع# عناصر نادرخاکی# فوگاسیته اکسیژن# پهنه سنندج- سیرجان#,
چکیده مقاله :
پلوتون های گرانیتوئیدی در پهنه سنندج-سیرجان میزبان دایک های پگماتیتی متعددی هستند. این پژوهش بر روی مطالعه شیمی کانی زیرکن در دایک های پگماتیتی گستره ملایر، بروجرد و شازند به منظور ارزیابی دمای تبلور زیرکن، فوگاسیته اکسیژن و نسبت Ce4+/Ce3+ و همچنین تعیین ضریب توزیع عناصر نادر خاکی، عناصر اورانیوم، توریوم، تالیم، نیوبیم و ایتریم متمرکز شده است. نمودارهای متمایزکننده گرانیتوئیدها از جمله Th در برابر Y و Yb/Sm در برابر Y و Nb، نشان داد، زیرکن های مورد مطالعه در گستره سنگ های سینیت پگماتیت قرار دارند. ضریب توزیع زیرکن/ سنگ کل نشان داد، بلورهای زیرکن غنی شدگی نسبت HREE به LREE دارند. شیمی زیرکن نشان داد، دایک های پگماتیتی ملایر و شازند دارای مقادیر Hf کمتر و تغییرات کمتر در REE نسبت به زیرکن های دایک پگماتیت بروجرد هستند که نشان‌دهنده نقش فرایندهای هیدروترمالی بعدی در تشکیل زیرکن های بروجرد است. دمای تبلور، فوگاسیته اکسیژن و نسبت های Ce4+/Ce3+ از دایک پگماتیتی ملایر به شازند و در نهایت بروجرد کاهش یافته است. شرایط احیایی ماگماتیسم، مقدار Th/U کمتر از یک و مقدار Y/Ho بالای 20 نشان می دهد، بنابراین این پگماتیت ها از لحاظ کانی سازی عقیم هستند.
The Granitoid plutons in the Sanandaj-Sirjan zone host numerous pegmatitic dikes. This study is focused on mineral chemistry of zircons in the pegmatite dikes in the Malayer, Boroujerd and Shazand district to evaluate zircon crystallization temperature, oxygen fugacity and Ce4+/Ce3+ ratio and also zircon/rock partition coefficients of REEs and U, Th, Ta, Nb and Y. Trace element discrimination digrams such as Th versus Y and Yb/Sm versus Y and Nb, indicated studied zircons were located in the syenite pegmatite field. Zircon/rock partition coefficients indicate that zircon granis are enriched in the HREE than LREE. Zircon chemistry show that zircon in the Shazand and Malayer pegmatite dikes have more Hf and less REE distribution than zircons in the Boroujerd pegmatite dikes. Consequently, it indicates the role of latter hydrothermal process in the formation of Boroujerd zircons. Crystallization temperature, oxygen fugacity and Ce4+/Ce3+ ratios decrease from Malayer to Shazand and finally Boroujerd pegmatite dikes. Reduced condition of magmatism, Th/U contents below 1 and Y/Ho content higher than 20 indicate that these pegmatities are barren.
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